Why is carbon so popular for making molecular backbones? Why don’t we instead use, say, oxygen for the same purpose? For one thing, carbon-carbon bonds are unusually strong, so carbon can form a stable, sturdy backbone for a large molecule. Perhaps more important, however, is carbon’s capacity for covalent bonding. Because a C atom can form covalent bonds to as many as four other atoms, it’s well suited to form the basic skeleton, or “backbone, ” of a macromolecule.
As an analogy, imagine that you’re playing with a Tinker Toy® set and have connector wheels with either two or four holes. If you choose the connector wheel with four holes, you’ll be able to make more connections and build a complex structure more easily than if you choose the wheel with two holes. A carbon atom can bond with four other atoms and is like the four-hole wheel, while an oxygen atom, which can bond only to two, is like the two-hole wheel.
Carbon’s ability to form bonds with four other atoms goes back to its number and configuration of electrons. Carbon has an atomic number of six (meaning six protons, and six electrons as well in a neutral atom), so the first two electrons fill the inner shell and the remaining four are left in the second shell, which is the valence (outermost) shell. To achieve stability, carbon must find four more electrons to fill its outer shell, giving a total of eight and satisfying the octet rule. Carbon atoms may thus form bonds to as many as four other atoms. For example, in methane (CH_4
4
start subscript, 4, end subscript), carbon forms covalent bonds with four hydrogen atoms. Each bond corresponds to a pair of shared electrons (one from carbon and one from hydrogen), giving carbon the eight electrons it needs for a full outer shell.
Why is
carbon
so
popular for making molecular backbones? Why don’t we
instead
use
, say, oxygen for the same purpose? For one thing, carbon-carbon bonds are
unusually
strong,
so
carbon
can
form
a stable, sturdy backbone for a large molecule. Perhaps more
important
,
however
, is
carbon’s
capacity for covalent bonding.
Because
a C atom can
form
covalent bonds to as
many
as four
other
atoms, it’s well suited to
form
the basic skeleton, or “backbone,
”
of a macromolecule.
As an analogy, imagine that you’re playing with a Tinker Toy® set and have connector
wheels
with either two or four holes. If you choose the connector
wheel
with four holes, you’ll be able to
make
more connections and build a complex structure more
easily
than if you choose the
wheel
with two holes. A
carbon
atom can bond with four
other
atoms and is like the four-hole
wheel
, while an oxygen atom, which can bond
only
to two, is like the two-hole wheel.
Carbon’s ability to
form
bonds with four
other
atoms goes back to its number and configuration of
electrons
.
Carbon
has an atomic number of six (meaning six protons, and six
electrons
as well
in a neutral atom),
so
the
first
two
electrons
fill the inner shell and the remaining four are
left
in the second shell, which is the valence (outermost) shell. To achieve stability,
carbon
must
find four more
electrons
to fill its outer shell, giving a total of eight and satisfying the octet
rule
.
Carbon
atoms may
thus
form
bonds to as
many
as four
other
atoms.
For example
, in methane (CH_4
4
start
subscript, 4,
end
subscript),
carbon
forms
covalent bonds with four hydrogen atoms. Each bond corresponds to a pair of shared
electrons
(one from
carbon
and one from hydrogen), giving
carbon
the eight
electrons
it needs for a full outer shell.